Coordination Polymerization in Water Affording Amorphous Polyethylenes
نویسندگان
چکیده
منابع مشابه
Coordination polymerization in water affording amorphous polyethylenes.
The coordination polymerization of ethylene in water as a reaction medium was studied. Rubbery amorphous branched polyethylene was obtained when a known cationic diimine-substituted methyl complex was employed as a catalyst precursor. High rates of up to 900 TOh(-1) (turnover frequency) were observed. In contrast to solution polymerization in an organic solvent, the rate of suspension polymeriz...
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ژورنال
عنوان ژورنال: Chemistry
سال: 2000
ISSN: 0947-6539,1521-3765
DOI: 10.1002/1521-3765(20001215)6:24<4623::aid-chem4623>3.0.co;2-